‘Clean Energy and Water Technologies’ is a blog, to create awareness, about clean technologies on water and energy, two fundamental factors, that determines human life on earth. The blog will post articles developments on such technologies, their sources, and their applications individually but more specifically on Renewable Hydrogen and Zero emission technologies.
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Thursday, July 11, 2013
How to control Carbon emissions in coal-fired power plants?
“Over two-thirds of today’s proven reserves of fossil fuels need to still be in the ground in 2050 in order to prevent catastrophic levels of climate change” – a warning by scientists.
There is a great deal of debate on climate change due to man-made Carbon emissions and how to control it without any further escalation. The first obvious option will be to completely stop the usage of fossil fuel with immediate effect. But it is practically not feasible unless there is an alternative Non-Carbon fuel readily available to substitute fossil fuels. The second option will be to capture carbon emission and bury them under ground by CCS (Carbon capture and sequestration) method. But this concept is still not proven commercially and there are still currently many uncertainties with this technology, the cost involved and environmental implications etc.The third option will be not to use fresh fossil fuel for combustion or capture and bury the Carbon emissions but convert the Carbon emissions into a synthetic hydrocarbon fuel such as synthetic natural gas (SNG) and recycle them. By this way the level of existing Carbon emission can be maintained at current levels without any further escalation. At least the Carbon emission levels can be reduced substantially and maintained at lower levels to mitigate climate changes. It is technically feasible to implement the third option but it has to be implemented with great urgency.
One way of converting Carbon emission is to capture and purify them using conventional methods and then react with Hydrogen to produce synthetic natural gas (SNG)
CO2 + 4 H2 ----------> CH4 + 2 H2O
The same process will be used by NASA to eliminate carbon built-up in the flights by crew members during their long voyage into the space and also to survive in places like Mars where the atmosphere is predominantly carbon dioxide. But we need Hydrogen which is renewable so that the above process can be sustained in the future .Currently the cost of Hydrogen production using renewal energy sources are expensive due to high initial investment and the large energy consumption.
We have now developed a new process to generate syngas using simple coal, which is predominantly Hydrogen to be used as a Carbon sink to convert Carbon emissions into synthetic natural gas (SNG). The same Hydrogen rich syngas can be directly used to generate power using gas turbine in a simple or combined cycle mode. The Carbon emission from the gas turbine can be converted into SNG (synthetic natural gas) using surplus Hydrogen-rich syngas. The SNG thus produced can be distributed for CHP (combined heat and power) applications so that the Carbon emission can be controlled or distributed. By implementing the above process one should be able to maintain Carbon at specific level in the atmosphere. Existing coal fired power plants can retrofit this technology so that they will be able to reduce their Carbon emissions substantially; they can also produce SNG as a by-product using their Carbon emissions and achieve zero Carbon emission at their site while generating revenue by sale of SNG.
Coal is the cheapest and widely used fossil fuel for power generation all over the world. Therefore it will be a win situation for everyone to use coal and also to reduce Carbon emissions that can address the problems of climate change. Meanwhile research is going on to generate renewable Hydrogen cheaply directly from water using various technologies. But we believe we are still far away from achieving this goal and we require immediate solution to address our climate change problems.
Recently BASF made a press release :www.basf.com/group/pressrelease/P-13-351 claiming a break-through technology to generate Hydrogen from natural gas without any CO2 emissions.