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Showing posts with label hydrogen car. Show all posts
Showing posts with label hydrogen car. Show all posts

Wednesday, April 19, 2017

CAPZ desalination technology uses only Sun,Sea and WInd !


CAPZ (Clean water at affordable price with zero discharge) is a new desalination concept that separates seawater into fresh drinking water and industrial salt both simultaneously using only sun and wind power. Seawater is nothing but fresh water in abundance with valuable mineral salts dissolved in it. These minerals include Sodium, Potassium, Lithium and Magnesium and a host of other minerals in traces. It requires a holistic approach to separate them in their pure form along with fresh water for potable and industrial applications. CAPZ technology precisely attempts to do that so that the seawater intake can be put into huge economic usage while reducing or eliminating completely the discharge of highly saline effluent contaminated with chemicals back into the sea. With increasing demand for fresh water and depleting sources of fresh water due to natural and man-made causes , sea water has become an important source for fresh drinking water. Sea water is not only a source of fresh water but also a new source of clean Hydrogen an energy of the future. It requires only sun ,sea and wind to achieve this!

Wednesday, January 6, 2016

Which car Hydrogen, Fuel cell or Electric that will win the race?


Automobile industry has come a long way since the time of Henry Ford. The internal combustion engine that drives the modern car is slowly but steadily evolving into an emission free engine. The carbon pollution has caused globe to warm and changed the climate and also caused respiratory illness for millions of people around the world for decades. The Carbon pollution was completely ignored in the past while other design features of the car have undergone massive changes. However, when the smog and deteriorating air quality of Delhi and Beijing was beamed around the world in our TV sets, people realized how vulnerable they are to carbon pollution. But how to eliminate the Carbon emission from our automobiles? 1.The simple answer is to substitute the fossil fuels we use every day such as Petrol and Diesel with Carbon free fuel such as Hydrogen. Hydrogen being a light gas it has to be compressed and liquefied so that it can occupy less space. However, it requires a special ‘cryogenic tank’ to store liquid Hydrogen at – 253 C. BMW has already produced a commercial vehicle and it is in the market. However, the Hydrogen dispensing stations are limited in numbers. It uses existing internal combustion engine suitably modified for Hydrogen fuel so that they can use existing infrastructure that produces their petrol engines. There is no carbon emission except for water vapour. However, Hydrogen should be generated using renewable energy sources such as solar or wind. Hydrogen generated by reformation of natural gas will still have a Carbon foot print. It can be classified as a Carbon free car depending upon how Hydrogen is generated. However, producing liquid hydrogen or filling in a cryogenic tank is not commercially feasible for individual household. Hydrogen supply will have to be a centralized filling station. BMW has recently focussing their attention towards Fuel cell car. While those early vehicles were fun to drive, they suffered from the inefficiencies of super-cooling the liquefied hydrogen, and the hydrogen vaporizing in storage. Around the turn of the century, BMW began to research the hydrogen-powered, fuel-cell electric vehicle as an alternative to the hydrogen-powered combustion engine. 2.The other alternative is to substitute fossil fuel with compressed Hydrogen that generates an electric power using Fuel cell that drives the motor and the car. Here both fossil fuel and internal combustion engine are substituted with Hydrogen fuel and Fuel cell. This is a marked deviation from a conventional car. Honda of Japan was the first to introduce a commercial car using a Fuel cell. It uses compressed Hydrogen at 70 Mpa pressure that supplies Hydrogen to PEM (proton exchange membrane) Fuel cell that generates power that drives the motor and the car. There is no emission except for water vapour. The car runs smoothly and silently because there is no mechanical engine or moving part. It is truly a Carbon free car if the Hydrogen is generated from a renewable energy source such as solar or wind. It is ideal for houses with roof top solar panels. However, one has to install a water purifier, an electrolyser, a compressor and a compressed tank for Hydrogen storage. If the Hydrogen is generated by steam reforming of Natural gas, then it will have a Carbon footprint and cannot be classified as carbon free car. Generation of Hydrogen using roof top solar panel, electrolysis and compression is possible by individual households but it involves still some risk due to the explosive nature of Hydrogen. A centralized Hydrogen dispensing is still a safer method. Toyota Mirai Fuel cell car is a new model introduced by Toyota motor Co of Japan. It too has certain additional features such as a power generator for a remote households or camps. 2.The third alternative is to eliminate fuel as well as the engine completely; instead supply power to the motor from a storage battery. Here there is no emission or noise because there is no engine or moving parts similar to Fuel cell car. However, the battery is heavy and occupies a large space and it requires frequent charging from an external power source. The power often comes from the main power grid which carries the power generated from a power station which invariably uses fossil fuel. Though there is no Carbon emission from the electric car it still has Carbon footprint. However, if the power is generated from a renewable energy source such as solar and wind then it can be classified as Carbon free car. It is ideal for houses with roof top solar panels. However, it should be connected to the power grid in parallel. Alternatively, it can be connected to a storage battery if there is no grid. The Lithium ion battery pack in Tesla Roadster weighs 990 pounds, stores 56 kWh of electric energy, and delivers up to 215 kW of electric power. Tesla battery packs have the highest energy density in the industry. To achieve this energy density, Tesla starts with thousands of best-in-class Lithium-ion cells and assembles them into a liquid-cooled battery pack, wrapped in a strong metal enclosure. The battery is optimized for performance, safety, longevity, and cost. The cells used in a Roadster employ an ideal chemistry for electric vehicles Nickel Metal Hydride (NiMH) batteries are commonly used in hybrid cars. However, a 56 kWh NiMH battery pack would weigh over twice as much as the Roadster battery. Instead, Tesla uses Li-ion battery cells which dramatically decrease the weight of the Roadster pack and improve acceleration, handling, and range.
With Lithium-ion chemistry, there is no need to drain the battery before recharging - there is no “memory effect”. Roadster owners simply "top-off" each night.However long term supply of Lithium is still an issue. Each of the above cars have their own advantages and disadvantages. However, Fuel cell cars have certain advantages over Electric cars in spite of the advancement in battery technology primarily due to the weight of the battery and frequency and time required to charge the battery. Fuel cell car has a capacity to store Hydrogen fuel as well as to generate power onsite and this advantage will go a long way to make fuel cell cars truly carbon free not only for transportation but also for stationery power generation in remote locations. A large scale deployment of renewable energy generation such as solar and wind around the world can deliver a Car that is truly carbon free. However fossil fuel power generation will continue for years to come as the new technologies are developed to generate power using fossil fuel without emitting Carbon emission such as Carbon recycling. The real winner of the car race will depend upon how a Carbon emission free power generation technology will emerge in the future. Whatever may the power technology Fuel cell will be here to stay and if a cheap alternative catalyst is developed for Fuel cell then the race will be well and truly on. (Ref : Honda, Toyota and Roadster websites)

Friday, March 21, 2014

It is time to switch over from Carbon to Hydrocarbon


When Carbon emission is high and the globe is warming due to such emissions then the simple and immediate solution to address this issue is to convert Carbon into Hydrocarbon, and the simplest Hydrocarbon is Methane (CH4).By simply introducing Hydrogen atom into Carbon atom the entire fuel property changes. For example the heating value of coal is only 5000-6500 kcal/kg at the maximum while the heating value of Methane (natural gas) increases to 9500 kcal/m3 by the above conversion. It means the same power generated by coal can be generated by using almost half the quantity of natural gas. Converting Carbon into substituted natural gas (SNG) is one way of addressing climate change in a short span of time. By switching over to SNG from coal will reduce the CO2 emission almost by 50%. Global warming due to GHG emission has become a serious environmental issue in recent times and more and more investments are made on renewable energy projects such as solar and wind etc. In spite of the major thrust on renewable energy projects the main source of power is still generated around the world using fossil fuel especially Coal due to its abundance and low cost. Moreover the investment already made on fossil fuel infrastructures are too big to be ignored and investment required to substitute coal-fired power plants by renewable energy are too large and gestation periods are too long to maintain the current electricity demand and to meet the future demands. The cost of renewable energy also is high and there is great resistance by consumers to switch over to renewable energy. Many Governments are reluctant to subsidize renewable energy due to their financial constraints. That is why countries like China which is growing at the rate of more than 8% pa are trying to decrease the ‘Carbon intensity’ rather than closing down the coal–fired power plants by setting up SNG (synthetic natural gas) plants by gasification of coal . This will reduce their Carbon emissions almost by 50% surpassing all other countries around the world in short span of time, thus meeting their emission targets agreed in “Kyoto protocol”. They can also meet the increasing electricity demand by using “syngas” generated by coal gasification plants, while reducing the Carbon pollution. They will also be able to produce Diesel and Gasoline from coal similar to the “SESOL” plant in South Africa which is already operating successfully for the past 50 years. “Leveraging Natural Gas to Reduce Greenhouse Gas Emissions” – a summary report by Center for Energy and Climate Solutions (C2ES) have highlighted the following in their report. “Recent technological advances have unleashed a boom in U.S. natural gas production, with expanded supplies and substantially lower prices projected well into the future. Because combusting natural gas yields fewer greenhouse gas emissions than coal or petroleum, the expanded use of natural gas offers significant opportunities to help address global climate change. The substitution of gas for coal in the power sector, for example, has contributed to a recent decline in U.S. greenhouse gas emissions. Natural gas, however, is not carbon-free. Apart from the emissions released by its combustion, natural gas is composed primarily of methane (CH4), a potent greenhouse gas, and the direct release of methane during production, transmission, and distribution may offset some of the potential climate benefits of its expanded use across the economy. This report explores the opportunities and challenges in leveraging the natural gas boom to achieve further reductions in U.S. greenhouse gas emissions. Examining the implications of expanded use in key sectors of the economy, it recommends policies and actions needed to maximize climate benefits of natural gas use in power generation, buildings, manufacturing, and transportation. More broadly, the report draws the following conclusions: •The expanded use of natural gas—as a replacement for coal and petroleum—can help our efforts to reduce greenhouse gas emissions in the near- to mid-term, even as the economy grows. In 2013, energy sector emissions are at the lowest levels since 1994, in part because of the substitution of natural gas for other fossil fuels, particularly coal. Total U.S. emissions are not expected to reach 2005 levels again until sometime after 2040. • Substitution of natural gas for other fossil fuels cannot be the sole basis for long-term U.S. efforts to address climate change because natural gas is a fossil fuel and its combustion emits greenhouse gases. To avoid dangerous climate change, greater reductions will be necessary than natural gas alone can provide. Ensuring that low-carbon investment dramatically expands must be a priority. Zero-emission sources of energy, such as wind, nuclear and solar, are critical, as are the use of carbon capture-and-storage technologies at fossil fuel plants and continued improvements in energy efficiency. • Along with substituting natural gas for other fossil fuels, direct releases of methane into the atmosphere must be minimized. It is important to better understand and more accurately measure the greenhouse gas emissions from natural gas production and use in order to achieve emissions reductions along the entire natural gas value chain.” Countries like India should emulate the Chinese model and become self-sufficient in meeting their growing energy demand without relying completely on imported Petroleum products. Import of petroleum products is the single largest foreign exchange drain for India, restricting their economic growth to less than 5%. Countries that rely completely on coal-fired power plants can set up coal hydro-gasification and gasification plants to reduce their Carbon emissions in the immediate future while setting up renewable energy projects as a long-term solution. Transiting Carbon economy into Hydrogen economy is a bumpy road and it will not be easy to achieve in a short span of time. The logical path for such transition will be to switch coal based power generation into gas based power generation for the following reasons. The largest Carbon emissions are from power generation and transportation. Transportation industry is already going through a transition from fossil fuel to Hydrogen. More future cars will be based either on Fuel cell or Electric and in both cases the fuel is the critical issue. Battery technology also will be an issue for Electric cars. It is more practical to generate Hydrogen from natural gas and to set up Hydrogen fuel stations than generating Hydrogen from solar powered water electrolysis. With improvement on Fuel cell technology it is more likely that PEM Fuel cell may be able to operate on Hydrogen derived from natural gas that is completely free from any Sulphur compounds. Even for Electric cars, natural gas will play an important role as a fuel for power generation and distribution in the near future as we transit from Carbon economy to full fledged Hydrogen economy. Countries like India with highest economic growth will have to be pragmatic by setting up more SNG plants with indigenous coal than depending on imported LNG. India has only two LNG terminals currently in operation but do not have gas transmission infrastructure. With increasing demand for natural gas from all over the world and lack of LNG receiving terminals, India will have to face a serious fuel and power shortage in the future. By installing more coal gasification and SNG plants with down-stream products like like Diesel and petrol, India can overcome the fuel and power shortage. In fact India set up the first coal gasification and Ammonia and Urea plant in Neyveli (Neyveli Lignite Corporation) way back in Fifties after her independence and it is time to visit the past. Renewable energy is certainly the long term solution for energy demand but we have to consider the amount of GHG emission associated with production PV solar panels, wind turbines and batteries. There is no easy fix to reduce GHG emission in short span of time but switching Carbon to hydrocarbon will certainly reduce the emissions scientists are advocating and water (steam) is the key to introduce such Hydrogen atom into the Carbon atom. That is why we always believe “Water and Energy are two sides of the same coin” and renewable Hydrogen will be the key to our future energy. President Obama's recent announcement of Carbon reduction plan by coal-fired power plants in USA is a bold step in the right direction.A more ambitious plan may be required to avoid catastrophic climate change that might cost billions of dollar in health related issues and on rebuilding damaged infrastructure. For more information on the above topic please refer to the following link: Source: Harvard University Link: Coal to Natural gas Fuel switching and Carbon dioxide (CO2) emission reduction. Date: Apr 2011. Author: Jackson Salovaara.

Monday, August 19, 2013

Clean power and water for remote island communities


Most of the renewable energy projects that are currently set up around the world are grid connected with feed-in power tariff arrangement. People can generate their own electricity by solar/wind to meet their demand and supply the surplus power to the grid at an agreed power rates. They can also draw power from the grid if there is any short fall in their production of renewable energy. It is two way traffic. There is an opportunity for people to generate revenue by sale of surplus power. It is an incentive for people to invest on renewable energy and that is why the investment on renewable energy has steadily increased over a period of time. But this is not the case with many developing and under developed countries. The situation is still worse in many islands where there is no centralized power generation at all or power distribution through grids. They depend on diesel generators. Even to transport diesel from mainland they have to use diesel operated boats. They have no drinking water even though they are surrounded by sea. I happened to visit a remote island in PNG few years ago and saw the plight of those people first hand. They live in absolute poverty and nobody cares to provide them a solution. Their voices are never heard and permanently drowned in the deafening roar of the sea. The problems of supplying clean power and water to these remote islands are not only political but also technical and commercial in nature. One has to use only commercially available systems and components which are basically meant for a single or three phase grid connected power supplies. Even though renewable energy sources basically generate only direct current (DC), one has to convert them into alternate current (AC) for easy distribution and to utilize appliances which are basically designed for AC operations. Isolated communities like islands can use direct current and also use DC operated appliances because they are commercially available and they are more efficient. Anyhow most of the house appliances need DC supply and AC/DC converters are commonly used for this purpose thus sacrificing efficiency in the process. They also need better storage solutions because they are not connected to the grid and they have to necessarily store power for several days. Some of these islands are connected with inefficient wind turbines backed by diesel generators. It is an absolute necessity to incorporate a long term storage capabilities in the system if one has to provide a continuous power and clean water. If the wind velocity is not sufficient (during off seasons) or if there is no sun (cloudy) for days together and if there is not sufficient storage capacity, then all the investment made on the project will be of no use. Any half baked solutions will not serve the real purpose. There are also commercial problems because a well designed system will cost more, which will eventually increase the power tariff. Unless the Government subsidizes the power sufficiently, people cannot afford to pay for their electricity or water. It requires a careful planning and community consultations to set up a ‘stand alone renewable energy projects in islands’. Governments in the pacific islands should act with great urgency because there is also a risk of inundation by sea level rising due to global warming. We are in the process of designing a solution to provide such islands with clean power, clean drinking water and even wireless connectivity for schools so that children can get education. It may sound ambitious but it is the first step one has to take into long journey of sustainability and self reliance by these isolated communities. There is a good possibility that such island may one day become completely independent and self sufficient with clean power and water. The same solution can be implemented in other countries too. Many countries have necessary infrastructure to generate and distribute power yet they suffer regular power cuts and black outs due to inefficiencies in their system. Our proposed solution can provide uninterrupted clean power and water because the system will have long duration centralized energy storage. We have made a detailed analysis of various alternatives available for the above purpose using Homer hybrid solution software. The solution proposes a PV solar with storage solutions using battery bank as well as Fuel cell back up. The solution also proposes long duration of storage ranging from few hours up to a fortnight .It is a standalone system with complete energy management and suitable for remote operations. The solution can also incorporate wind turbine in addition to PV solar depending upon the location and wind velocity profile. The model is to supply clean power and drinking water for 600 families with an average 3 people in a family. The system will supply power at the rate of 1.50kwhrs/day/person (1800 x1.5 = 2700kwhrs/day) and drinking water at the rate of 200 lits/day/person (1800 x 200 lit/person= 360,000 lits/day).The power for a desalination plant will be 1980 kwhrs/day. The system is designed for a total power generation capacity of 4680Khwhrs/day. The model is based on battery storage as well as based on Hydrogen storage with varying durations. Comparative analysis is shown in the figures. The first window is based on PV solar with 2 months Hydrogen autonomy. The third window is based on PV solar with battery 5 days and 17 hrs Hydrogen autonomy. The fourth and fifth window is based on PV solar with battery 17 hrs and Hydrogen 18 hrs storage autonomy with varying panel cost. The sixth window is based on PV solar with 172 hrs (one week) battery autonomy. The resulting analysis indicates that a centralized Hydrogen storage with Fuel cell back up offers the most economical solution even though the power tariff is higher than a system with battery storage. The investment for long duration battery storage is almost double that of Hydrogen based solution. The cost can further be reduced if and when the Electrolyzers as well as Fuel cells are manufactured on mass scale. The added advantage with this system is it can also provide Hydrogen fuel for Fuel cell cars and boats substituting diesel. One day it may become a reality that these isolated islands can become completely self- sufficient in terms of water, fuel and power with no greenhouse gas emissions. This solution can be replicated to all the islands all over the world. Note: The above system can also be installed in many developing countries in Africa which is an emerging market. An Africa-Australia Infrastructure Conference will be be held in Melbourne, Australia on 2-3 September 2013 and it will offer a platform for Australian companies to invest in Africa on infrastructural projects.

Thursday, June 14, 2012

Changing winds and storing technologies


Wind energy is one of the fastest growing renewable energy sources in the world and in 2011 the global market grew by 6% with 40.5 GW new powers brought online, according to Global Wind Report. However storage of intermittent renewable energy is a critical contributing factor in renewable energy development. A study was conducted by University of California on behalf of California Energy Commission on the economic and environmental impact of four energy storage technologies and the ways to improve the energy efficiency of wind energy. When there is a strong wind there is no demand for power, and when there is a high demand for power there is no wind. This anomalous supply demand gap demands a reliable way of storing wind power during high wind velocity periods. They examined four energy storage technologies namely 1.lead acid batteries, 2. Zinc Bromine flow batteries, 3.Hydrogen electrolyzer and Fuel cell storage system and 4.Hydrogen option to fuel Hydrogen cars with Hydrogen. By using NREL (national Renewable Energy laboratory) computer simulation model HOMER for high wind penetration of 18% in California, they concluded that Hydrogen storage is the most cost effective than other battery storage technologies and using Hydrogen to fuel Hydrogen cars is economically attractive than converting Hydrogen into Electricity. The environmental impact of using Hydrogen is benign compared to batteries with their emissions. “The key findings of this experiments are as follows: Energy storage systems deployed in the context of greater wind power development were not particularly well utilized (based on the availability of “excess” off-peak electricity from wind power), especially in the 2010 time frame (which assumed 10% wind penetration statewide), but were better utilized–up to 1,600 hours of operation per year in some cases–with the greater (20%) wind penetration levels assumed for 2020. The levelized costs of electricity from these energy storage systems ranged from a low of $0.41 per kWh—or near the marginal cost of generation during peak demand times—to many dollars per kWh (in cases where the storage was not well utilized). This suggests that in order for these systems to be economically attractive, it may be necessary to optimize their output to coincide with peak demand periods, and to identify additional, value streams from their use (e.g., transmission and distribution system optimization, provision of power quality and grid ancillary services, etc.). At low levels of wind penetration (1%–2%), the electrolyzer/fuel cell system was either inoperable or uneconomical (i.e., either no electricity was supplied by the energy storage system or the electricity provided carried a high cost per MWh). In the 2010 scenarios, the flow battery system delivered the lowest cost per energy stored and delivered. At higher levels of wind penetration, the hydrogen storage systems became more economical such that with the wind penetration levels in 2020 (18% from Southern California), the hydrogen systems delivered the least costly energy storage. Projected decreases in capital costs and maintenance requirements along with a more durable fuel cell allowed the electrolyzer/fuel cell to gain a significant cost advantage over the battery systems in 2020. Sizing the electrolyzer/fuel cell system to match the flow battery system’s relatively high instantaneous power output was found to increase the competitiveness of this system in low energy storage scenarios (2010 and Northern California in 2020), but in scenarios with higher levels of energy storage (Southern California in 2020), the electrolyzer/fuel cell system sized to match the flow battery output became less competitive. The hydrogen production case was more economical than the electrolyzer/fuel cell case with the same amount of electricity consumed (i.e., hydrogen production delivered greater revenue from hydrogen sales than the electrolyzer/fuel cell avoided the cost of electricity, once the process efficiencies are considered). Furthermore, the hydrogen production system with a higher-capacity power converter and electrolyzer (sized to match the flow battery converter) was more cost-effective than the lower-capacity system that was sized to match the output of the solid-state battery. This is due to economies of scale found to produce lower-cost hydrogen in all cases. In general, the energy storage systems themselves are fairly benign from an environmental perspective, with the exception of emissions from the manufacture of certain components (such as nickel, lead, cadmium, and vanadium for batteries). This is particularly true outside of the U.S., where battery plant emissions are less tightly controlled and potential contamination from improper disposal of these and other materials is more likely. The overall value proposition for energy storage systems used in conjunction with intermittent renewable energy systems depends on diverse factors: The interaction of generation and storage system characteristics and grid and energy resource conditions at a particular location The potential use of energy storage for multiple purposes in addition to improving the dependability of intermittent renewable (e.g., peak/off-peak power price arbitrage, helping to optimize the transmission and distribution infrastructure, load-leveling the grid in general, helping to mitigate power quality issues, etc.) The degree of future progress in improving forecasting techniques and reducing prediction errors for intermittent. Electricity market design and rules for compensating renewable energy systems for their output”. Hydrogen storage and Hydrogen cars hold the key for future renewable energy industries and Governments and industries should focus on these two key segments.