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Showing posts with label Renewable Hydrogen. Show all posts
Showing posts with label Renewable Hydrogen. Show all posts

Saturday, September 4, 2021

What future holds for energy and climate?

Energy industry is at a crossroad. It must now find a new direction to address the climate issue while to continue to supply energy to the world. The options are very clear. It can find new ways and means to genuinely address some of the mistakes of the past by inventing new methods to address the problem irrespective of the cost involved because time is not in our favour. Alternatively, one can redirect the issue using new terminologies and jargons and temporarily buy some time till finding an alternative and lasting solution to the problem. The first option will take time and cost more, and the second option may not take time and cost less. It seems most of the companies are choosing the second alternative. But how? Renewable energy is defined as “a source of energy that is available from the nature that can be constantly replenished”. This will guarantee the sustainability. But we are used to Carbon based fuels and technologies and therefore we also need a renewable Carbon that can substitute fossil fuels so that existing technologies for power and transportation can be used. Biomass is also derived from plants and animals like fossil fuels, but it is different in terms of time scale, and it can be replenished quickly unlike fossil fuels. It is basically made up of Carbon, Hydrogen and additionally oxygen, like fossil fuels such as coal, oil and gas but free from sulphur. Therefore, one can use the same technology such as combustion, gasification and pyrolysis etc and convert a biomass into energy, chemicals and fuels while claiming them as “renewables”. It will require oxy-combustion and gasification methods and unfortunately usage of pure Oxygen will be inevitable.Therefore, both Carbon as well as Hydrogen derived from biomass becomes “Green” and “renewable”. In addition "Green Hydrogen" using renewable energy sources such as solar and wind by water electrolysis will help decarbonisation by capturing and converting CO2 emissions into a Syngas. It requires a steep fall in the cost of renewable electricity to less than $20/Mwh and Carbon emission to be taxed at least @ $250/Mt to discourage fossil industry. Once we establish green and renewable Carbon and Hydrogen then it is only a matter of generating a syngas, combination of Hydrogen and Carbon monoxide with various ratios to synthesis various chemicals including bio crude oil that leads to refineries to produce petrol, diesel and aviation fuels. We will be back into the game but with different brand called “Green and renewable”; it is "an old wine in a new bottle" Everybody is happy and politicians can now heave a sigh of relief and feel comfortable. One can also use “blue hydrogen’ as a mix to green hydrogen and synthesis various downstream chemicals such as Ammonia, urea etc. Thus they can use them to decarbonise the fossil economy. In either way there is still an issue of CARBON EMISSION that needs to be addressed. They may claim biofuel as Carbon neutral, but it will not stop the increasing concentration of GHG into the atmosphere or climate change. Therefore Carbon tax will be inevitable. Bioenergy and renewable energy may increase the sustainability but will not address the issue of global warming and climate change. Nature does not discriminate between ‘bio-carbon’ and ‘fossil carbon’. Only “Carbon Recycling Technology” can address the problem of global warming and climate change. The simplest method will be to to collect CO2 emission from all petrol and diesel engines in a liquid form using a retrofittable device in the vehicle and convert them in a centralised facility to Syngas using renewable Hydrogen .The syngas can be converted into renewable crude using F-T reaction hat can be processed in a refinery for recycling into petrol, diesel and aviation fuel so that we can eliminate technologies such as large batteries and Fuel cells. By this way we can ensure the CO2 level in the atmosphere is stabilised and existing infrastructures are utilised. The availability of biomass for a radical change will be an issue especially in Asia where growing population requires more land for agriculture and deforestation is a common problem. Perhaps we need completely a new electricity generation technology that can "drive electrons to flow in a super conductor" and a magnetic storage using a cryogenic fluid. Unfortunately not many researchers are working in this direction.

Friday, April 23, 2021

WATER AND ENERGY ARE TWO SIDES OF THE SAME COIN

 




I always believed one can create energy from water and water from energy. Ancient Hindus believed water comes from fire and fire comes from water, two fundamental building blocks out of five elements that are necessary for Creation.

Water (H2O) is made up of two atoms of Hydrogen and one atom of Oxygen. The structure itself is an absolute beauty because it contains both reductant and oxidant tied up inseparably in such a way it requires enormous energy to separate them. Individually Hydrogen forms an explosive mixture with air on combustion. People familiar with Oxy Hydrogen will know such a stoichiometric mixture of Hydrogen and Oxygen in gaseous form by water electrolysis generate a flame that can cut an iron piece but leaves water on condensation. Current methods of Electrolysis using PEM (proton exchange membrane) can not only split water into Hydrogen and Oxygen but also separates them simultaneously into two different gases. Fuel cell just reverses the above reaction by combining Hydrogen and Oxygen generating electrical power and heat as a by-product. The fundamental facts about water and energy remain the same for millennia.

We are now facing a new challenge of global warming and climate change that is supposed to be caused by the unabated emission of CO2 into the atmosphere by the combustion of fossil fuels. The world is now gearing up to achieve net-zero emission by 2050. In my opinion, it is not such a big challenge, but the world has neglected emissions for too long. The science of electricity generation using electromagnetism is far from perfect in the sense it failed to consider the emissions by combustion of fossil fuels. The simple solution is to reduce the oxides of Carbon back into Carbon so that there will be zero-emission. Unfortunately, we never used pure Oxygen for combustion but air because it is readily available and cheap to use. But it generates not only CO2 but also NOx, NO2, H2S, SO2, etc. all contributing to air pollution which is now affecting the world by way of global warming and climate change. The CO2 level in the atmosphere has now reached 415 ppm which is only part of the anthropogenic CO2 emission since the industrial revolution. About a third of it has been absorbed by the ocean thus acidifying the seawater. The pH level of the sea is slowly but steadily decreasing making it more acidic. Thanks to the enormous buffering capacity of the sea and such a change are hardly noticeable. But it will soon change the chemistry of the water. It is a complex situation with the changing chemistry of seawater due to absorption of CO2, heat, increasing salinity. Sea levels rise due to melting of glaciers, constant discharge of highly concentrated effluent discharges from seawater desalination plants and power plant cooling towers, etc.  Climate modeling in the future will be challenging.

I previously posted an article on “Zero-emission baseload power using only sun and sea”. It has attracted many viewers worldwide especially in my blog/: https://www.clean-energy-water-tech.com.

I have already filed a provisional patent application with IP Australia, and I am in the process of filing an international patent application so that I can secure an IP with a value. The technology is based on a couple of well-proven concepts and it will not be difficult to implement them commercially. A couple of multinational companies has already endorsed my process they are even willing to take part as EPC (engineering, procurement, and construction) contractors.

I am planning to seek donations and contributions from my worldwide audience by way of crowdfunding to secure an IP worldwide so that I can practically contribute my knowledge and experience to address one of the greatest challenges of global warming and climate change.

Please watch this blog and my next article will elaborate on my patented technology.

 CARBON RECYCLING TECHNOLOGY (CRT) also known as RAMANA POWER CYCLE (RPC) FOR A ZERO EMISSION BASELOAD POWER USING ONLY SUN AND SEA.

I invite everyone to contribute by way of donations to my campaign at

  https://readyfundgo.com/?post_type=ignition_product&p=52427.

The funds will be used to seek international patent for my invention as an intellectual property. It will enable me to demonstrate further the invention by installing a 25 Mw baseload power plant with zero emissions using only sun and sea. It is a small beginning for a lasting solution for a net zero emission technology. It will also help reduce ocean acidification and help marine life including corals. It will be the new beginning !

Saturday, February 15, 2020

Ramana Power Cycle (RPC)


RPC is a newly developed patent (pending) technology from Australia to generate a base load power (24x7) using Renewable Hydrogen and CO2 with Zero emission,
The process discloses a method and system to generate CO2 from seawater along with Hydrogen using any renewable energy source to produce synthetic methane gas known as renewable synthetic methane (RSMG) to generate a base load power. The CO2 can be from various sources apart from sea such as power plants using fossil fuel, steel, cement, coke oven gas, or any syngas generated from various known methods from various sources such as steam methane reformer etc. The process can use any Oxy-combustion CO2 power cycle such as CES, Graz cycle, Allam cycle (using super critical CO2 as a working fluid) or a conventional combined cycle power plant using air combustion to generate a base load power 24 x 7 with ZERO EMISSIONS. The cost of power is estimated to be competitive even in the absence of Carbon pricing or Carbon tax. Needless to mention the unit cost of power can be further reduced by using Carbon pricing or Carbon tax. It is up to individual governments to introduce such a mechanism in order to deploy RPC on a larger scale.
The advantage with the system is it can generate electric power from CO2 with the highest electrical efficiency up to 70% while achieving Zero emissions. It effectively solves the global warming and climate changes problems using existing technologies and infrastructure without a need to develop a new power technology from scratch.
It can be retrofitted with any existing and operating fossil fuel-based power plant OR any large-scale renewable energy plant. It does not require storage batteries or any energy storing devices. The minimum viable capacity starts with 100 Mw and can be scaled up to 500 Mw and beyond and power can be exported to the grid directly through a substation. Optionally the process requires only sun and sea (ocean is the largest reservoir of Carbon, Hydrogen and heat to generate a base load power along with potable water with Zero Carbon emission and achieves circular economy).

Sunday, December 15, 2019

Can Hydrogen substitute Carbon and avoid catastrophic climate change?


 The answer is most likely NO for the following reasons.
It has been established that man-made GHG emissions mainly by CO2 is causing the globe to warm by a phenomenon known as “Greenhouse gas effect” triggering change in climate. Therefore, many are suggesting Hydrogen as an alternative clean fuel to reduce or eliminate CO2 emission. But replacing Carbon with Hydrogen we will only substitute Oxides of Carbon (CO2) with Oxides of Hydrogen (H2O). But water vapor too is a potent greenhouse gas GHG and it may enhance the warming of the globe by a phenomenon known as Feedback effect as explained by NASA and American chemical society (ACS) by the following references:

 Moreover, Renewable Hydrogen is still very expensive compared to Hydrogen derived from fossil fuel such as coal and gas even though cost of renewable energy has reduced substantially in recent past. By injecting valuable renewable Hydrogen into existing pipeline carrying natural gas one will generate additional issues because of varying physical and chemical properties of Hydrogen and its flammability and explosive nature compared to natural gas. Hydrogen is an unstable atom and readily forms a bond with Oxygen and Carbon and that is why Nature does not produce free Hydrogen. It requires a Carbon backbone. Only an emission free power generation technology can solve the problem of global warming. It is only possible by recycling Carbon (Carbon recycling technology) with the help of renewable Hydrogen and to achieve a circular economy. There is no shortcut.


Tuesday, September 24, 2019

Carbon Recycling Technology (CRT) is a potential solution for Zero Carbon Emission.

What is CRT?
CRT is a process technology that captures CO2 from existing and operating base load (24 x 7) power plants using fossil fuels and substituting the Oxygen in CO2 with renewable Hydrogen thereby converting CO2 into RNG (renewable natural gas). Then RNG becomes the renewable fuel for the above power plant. It is a perfect example of a circular economy with Zero Carbon emissions.
CRT becomes a link between fossil power industry and renewable industry, and it can achieve zero Carbon emission in the shortest possible time frame averting a catastrophic climate change.
Why CRT?
The climate change is a global issue and it requires a global solution and eliminating CO2 emission by few countries will not address the problem and it will require a collective solution. CRT can provide such a solution.
The world is now divided than ever before into two segments. One segment believes Carbon emission is causing global warming and climate change and therefore CO2 should be curtailed or eliminated completely, and all future energy should come only from renewable energy sources such as solar wind etc to avert climate change.

The other segment believes the science of climate change is not well established and dismisses the theory that CO2 causes global warming and climate change. They believe such a change is a natural phenomenon and it has nothing to do with CO2 emissions.  They fear by simply eliminating fossil fuel usage in the absence of a clear substitute the energy industry will be seriously disrupted causing economic collapse and the security of a nation. For example US has become the largest exporter of oil and gas in the world due to their aggressive policy of exploiting oil and gas reserves using techniques such as fracking. However these resources are finite and their CO2 emissions will become a stumbling block in the near future.
 It is a useless exercise to engage in argument without a clear path forward. But I am sure they will certainly agree and support a substitute fuel such as renewable natural gas (RNG) that can generate a base load power with zero carbon emission.
CRT will be able to convince both the above segment of people because it will meet the requirements of both the parties.
The bottom line is we need a system that can guarantee to generate an uninterrupted power 24 x7 with zero Carbon emission irrespective of a method we use if it is sustainable and environmentally friendly.
How do crew in space shuttle get rid of their CO2 emission from their cabin is shown below by NASA.
Carbon recycling technology is like the above process except CO2 is generated by combustion of natural gas as a by-product of base load power generation which is being removed and recycled in the form of RNG (renewable natural gas) using renewable
Hydrogen. Capture Carbon recycling in space

(Utility scale battery storage)
Methan from CO2SNG plant(Methanation plant for CO2 to SNG)
Renewable energy is a low efficient and intermittent source of energy and it may not meet the world’s energy requirement at the current rate. It will require massive energy storage technologies to be deployed in the shortest possible time frame. According to NREL report a 100 Mw PV solar with 240 Mwh storage battery will cost approx. USD 188 mil. To meet a base load power of 2400 Mwh/day the cost of the system will be USD 1.88 billion. The life of storage battery is assumed only at 12 years and will require replacement at least twice in 24 years of its life cycle. The same capacity 100 Mw combined cycle power plant using natural gas will cost only USD 105 mil with a life of at least 25 years. Therefore, renewable energy alone cannot solve the problem of climate change in its current form. It will be prudent to use renewable energy to generate renewable Hydrogen (RH) from water (even seawater) and use it to decarbonize the fossil economy. In fact, this is the solution  world needs right now.
Large(utility) scale battery will require massive amount of exotic material such as Lithium, Nickel, Cobalt etc which are not renewable and will have a large carbon footprint and disposal of depleted batteries will create massive environmental problems in the future. They are simply not sustainable.
Combined cycle power generation using natural gas is a proven technology that has been used for decades and all the infrastructure required are already in place.
What is involved in CRT?
CRT will involve the following three sections:
  1. Renewable energy facility such as PV solar, Concentrated solar or wind, geothermal, OTEC and hydro etc.
  2. Renewable Hydrogen facility to generate and store Hydrogen using the above renewable energy sources.
  3. Combined cycle base load power plant with CO2 capture and storage using either pre or post combustion technologies.
  4. Conversion of captured CO2 into renewable natural gas RNG which can substitute natural gas in the above base load power plant with zero Carbon emission.
There are number of renewable energy industries established all over the world in the past decade and they are currently operational. The lowest power tariff quoted by renewable energy industry in India is as low as $ 0.035/kwh making it an attractive clean energy source. There are issues in exporting it to the grid due to peak hour supply and demand gap. This renewable energy can be used to generate renewable Hydrogen (RH) by electrolysis of water. Hydrogen can be used as a storage medium to generate power during peak hours using fuel cells. It can also be used to fuel Hydrogen (Fuel cell) cars. Hydrogen cars have many advantages over battery cars based on life cycle assessment. Renewable Hydrogen (RH) is going to help accelerating the decarbonization process of the world soon.
Currently bulk of the power is generated using fossil fuel such as coal, oil and gas. The CO2 emissions can be reduced by 25% by simply switching over from coal to gas. Exiting coal fired power plants can be modified to gas fired plants by replacing their existing boilers. By using RNG the power plant can achieve zero carbon emission while generating base load power.
CRT is a simple and straight forward process technology that can avert global warming and climate change without disrupting existing fossil fuel infrastructure and its power generation while achieving ZERO CARBON EMISSION in the shorted possible time frame. It will promote renewable energy industries in a big way and help decarbonize our economy on a global scale. The cost of renewable energy should further come down so that renewable hydrogen (RH) as well as renewable natural gas (RNG) will become cheaper. Removal of fossil subsidies, taxing carbon emission and subsidizing renewable energy can facilitate such a transition and quicken the process of decarbonization and avert the climate change. A detailed financial model will reveal how quickly and effectively CRT can help countries reduce their emissions.
High CO2 emitting countries such as China, US, India, Australia, Japan, EU and others should adopt this technology .This technology is compatible with transportation technologies such as electric vehicles and Hydrogen (Fuel cell) vehicles because it can generate base load power (24 x 7) with Zero Carbon emission which are essential for the success of the above transport applications. WithoutCRT the transport applications will collapse even if they are "the state of art" technologies.


Tuesday, August 27, 2019

The real solution to Carbon problem

The real solution for Carbon problem:
When mother nature buried Carbon under the ground by way of fossil, we human beings mined them at enormous cost and added further value by combustion with air converting it into CO2 (carbon dioxide). In fact, we human beings added enormous value to carbon that remained buried (with zero value) for millennia. We were interested in the heat of combustion but forgotten about the CO2 emission. This is the fundamental flaw in the commercialization of thermal power using fossil fuels. Now there is a price to pay. There are only 2 options to overcome this problem.
1    We can completely ignore and ban fossil fuel all together at enormous cost (we have already invested in trillions in mining, processing, transporting and storing) and seek completely a new solution without any Carbon at all. This is unlikely to happen.
2      We can continue to use fossil fuel and generate base load power as we have been doing for decades but capture CO2 and convert it back into fuel so that it can be recycled with Zero CO2 emission. This is certainly feasible.
Many “so called innovators” are suggesting alternatives to fossil power generation using renewable source of energy. These sources were available with us from the beginning of the world as we know it, but they are intermittent. We are used to 24

x7 base load power using fossil fuels.
The real solution lies in using intermittent renewable energy to generate base load power (24 x 7) with zero Carbon emission. Renewable Hydrogen can achieve this goal. In doing so battery can also play a small role but not a major role. Couple of things should happen to achieve this goal.
1.     Capturing CO2 at the lowest cost. It can be best achieved using Oxy combustion of fossil fuel such as LNG (because it is a purified form of natural gas) using Brayton cycle with 100 % CO2 capture.
2.     Generate renewable Hydrogen (RH) using electrolysis using renewable energy source such as solar and wind etc. Technology is well proven and commercially available.
3.     Convert captured CO2 into CH4 using methanation reaction (which is already commercially practised) and recycling CH4 as a fuel to continue the base load power generation as usual. The newly generated CH4 becomes a renewable natural gas (RNG) by substituting fossil Hydrogen with renewable Hydrogen (RH). This technology developed by CEWT is known as Carbon Recycling Technology (CRT). It is a perfect example of a circular economy. Governments around the world should scrap fossil subsidies, tax Carbon @ $100.Mt ( at least) and offer liberal subsidies to renewable energy so that the cost of renewable hydrogen (RH) is at the lowest. CRT will allow Carbon to remain below ground as nature has done for several years. CRT will allow to run base load power (24 x 7) using RNG with ZERO CARBON EMISSION.

The above process is the only economical, commercial and environmental solution to the problem of global warming and climate change. All other methods will be expensive, time consuming with no guaranteed results and are unlikely to happen in the shortest time we have.
We at CEWT have the solution (not just theoretical but practically and commercially implementable immediately) and we seek like-minded partners and investors to team up with us so that we can show case the technology and implement them worldwide.








Friday, July 19, 2019

Renewable Hydrogen, an emerging alternative to fossil fuel


Fossil fuels such as coal, oil and gas have helped transformed our power and transport industries for decades till now. But recent geo-political situations, depleting fossil sources and Carbon pollution, global warming and climate change have raised serious questions about the future of fossil fuels. However, countries who have massively invested in fossil fuel infrastructure and who have been heavily relying on supply of fossil fuels have started realizing an inescapable truth that they are running out of time to find an alternative to fossil fuels. Recently Hydrogen has been suggested as an alternative source of energy and many countries are gearing up to promote Hydrogen on a massive scale. The countries who have been traditionally using fossil fuels are now focussing on generating hydrogen from fossil fuels as an easier option. But the basic problem with this approach is they still depend on fossil fuels which means they still contribute to Carbon emission and climate change. They can conveniently dispute or deny the fact that man-made Carbon emissions cause global warming in order to score political points among the ‘gullible public’. Democracy is all about numbers and as along as these number stack up the political parties will take advantage of the system and try to push their agenda. But all these efforts are only short term and they still cannot escape the truth that man made Carbon emission is transforming our world for the worst and the future looks bleak. However, there is a silver lining in the dark clouds of global warming and climate change in the form of renewable Hydrogen. It is now possible to generate Hydrogen using renewable energy sources such as Hydro, solar, wind, geothermal and OTEC (ocean thermal energy conversion systems) that can used not only decarbonize our present economy and also has the capacity to transform future energy and to a cleaner and more sustainable environment. It is now possible to achieve a circular economy in energy sector which means the CO2 emission from existing and operating power plants using fossil fuels can be reversed using renewable Hydrogen so that one can continue to generate power but with Zero Carbon emission. This is a huge transformation. However, the usage of fossil fuels will continue in other industries such as petrochemicals, polymers and additives, and other synthetic materials. But one can take advantage of using renewable Hydrogen even in such industries using Green Chemistry initiatives so that they can become more sustainable. However Renewable Hydrogen is currently very expensive though it is generated from abundantly available natural resources such as sun, wind and water because PV solar panels are made from high purity silicon material again made from simple sand. We cannot afford to take natural resources lightly because they are precious commodities. With limited usage of renewable energy at current levels the cost of PV solar panels is still very expensive but likely to come down as we deploy more and more solar panels in the future. We should also be careful how we use renewable Hydrogen. Our first and foremost usage of renewable Hydrogen should be to decarbonize the fossil economy and achieve a circular economy. It means we must convert CO2 emissions into renewable natural gas (RNG) using renewable Hydrogen so that the Carbon can be recycled indefinitely with Zero Carbon emission while power plants using fossil fuels can continue to generate a base load power. By this way we will be able to address two issues namely meeting the rising energy demand at a cheaper price while eliminating global warming and climate change. All other use of renewable hydrogen such as Hydrogen vehicles for transportation using fuel cell etc will be secondary because they are not our priority. If we can generate a base load power (24 x7) using renewable Hydrogen with zero Carbon emission, then that should be our focus whether we believe it climate science or not. This will also help us conserve fossil fuels that may be rarely used to meet certain critical needs while substantially reducing the carbon emission. Renewable hydrogen will require massive deployment of renewable energy projects all over the world. One can generate renewable energy and use it directly for domestic or commercial use. But they are intermittent and require large scale energy storage. Moreover, all HT transmission lines are old and designed for transmitting base load power. Such an approach will not help decarbonizing fossil economy currently widely used. That is why renewable Hydrogen will have to play a key role in the future energy mix. Renewable hydrogen can be used as a fuel for transport industries using fuel cell and Japan is leading the way in this field. But such an application has along way to go and it requires massive investment and creation of infrastructure by way of filling stations. Countries like Japan do not have vast land area for solar industries, and they are likely to use cheap nuclear power and sea water to generate large scale hydrogen infrastructure. By this way they can supply power to both hydrogen as well as electric (battery) vehicles. Alternatively, they are looking to import liquified hydrogen (LH2) from countries like Australia who are ready to use cheap brown coal to generate Hydrogen by gasification despite CO2 emissions. Currently Australian government is very keen to encourage LH2 from cheap coal. They have already approved a pilot plant in the state of Victoria and only future can tell whether such a decision is prudent or not. Japanese companies may prefer to invest in Australia to generate and export clean liquid hydrogen leaving behind all emissions including CO2 in Australia. They may generate LH2 from natural gas and export it to Japan, but it may not be acceptable by Japanese companies because it has a potential to poison the Platinum catalyst used in their Fuel cell cars. In fact, Australia has an enormous potential to generate renewable hydrogen and then use it locally as well as to export. This will be more sustainable in the long run.

Friday, May 10, 2019

It is time UN acted on climate change


Carbon emission caused by human beings has become a major issue for our environment and future economy due to changing climate. But there are still few countries who are sceptical about the science of climate change and reluctant to act and refuse to be a part of United Nation’s action on climate change. These countries are either fossil fuel producers such as coal, oil and gas or large economies who have been traditionally depending on usage of fossil fuel for their economy and security. The transition from Carbon economy to non-Carbon economy may not be easier for them in the absence of an alternative technology that can guarantee not only complete elimination of CO2 emission but also efficiency and sustainability. There is a strong political motivation too behind such dithering and they create a fear of slowing economy and large-scale unemployment among the people in the absence of a viable alternative energy source. Therefore, United Nation has an important role to play at this critical juncture of transition to non-carbon economy and save the planet earth from imminent danger of environmental and economic collapse. UN can also stop mass extinction of species and migration of refugees for a better life. UN was successfully able to bring together 174 countries to the negotiating table during Paris climate change conference. However, they failed to reach a unanimous Agreement and announce a concrete action plan to act. They failed to articulate the ways and means of reducing or eliminating man made CO2 emissions in a stipulated time frame. They also failed to bring powerful nations such as USA to the table which made the task even harder. But this situation can be changed if UN is able to articulate a concrete Action plan which is agreeable to all the parties involved. This is possible only if UN can address all the issues involved such as the alternative technology, funding, implementing in a stipulated time frame, measuring and monitoring the progress and achieving the final goal. UN should first be able to create the same level playing field where all Countries can take part equally without any discrimination. It depends completely on focussing the type of technologies to be deployed to achieve the above goals and It should be able to set a specific date to implement such a plan. Currently renewable energy is considered as one of the alternatives along with renewable Hydrogen which can act both as an energy storage and as well as energy carrier. But renewable Energy is intermittent and energy storage has become part of the system. With our limited experience in renewable energy deployment over a decade renewable energy alone Cannot be the solution to address the issue of CO2 emissions. One must estimate the life cycle CO2 emissions of hardware used in renewable energy systems such as PV solar panels, Solar concentrators, wind turbines, storage batteries. Renewable Hydrogen generators, Fuel cells etc. Each of them has their own Carbon footprint that must be incorporated in life cycle assessment. Similarly, even fossil fuel-based power generators such as boilers, steam or gas turbines, pumps and compressors etc too have Carbon footprint that should be assessed. Carbon footprint should be assessed as fixed carbon footprint and variable carbon footprint and then these data should be used to arrive at the Carbon footprint to generate power (tons of CO2/Mwh) Once a life cycle assessment of their Carbon footprint is estimated then it will be easier to rate each technology based on their “Carbon Rating” which will be a measure of their Carbon footprint. The Carbon rating is measured and allocated “number of stars” based on Carbon footprints. Lowest emitting technology will be rated with highest number of stars while highest emitting technologies will get the lowest number of stars. Carbon rating will be a good measure to assess the technology that can be used worldwide. Countries who are reluctant to reduce CO2 emissions will be discouraged to participate in government and private tenders worldwide and exports. Such countries will be treated as “Pariahs” and rejected by consumers due to their low Carbon rating. Technologically advanced countries or companies who can use fossil fuel but with lowest or Zero CO2 emissions will also be able to compete with renewable energy technologies. Carbon Rating will offer everybody the same level playing field. Carbon is the fundamental building block of organic life on earth which is essential for human survival but unabated CO2 emission by human activities is the culprit. I strongly believe Zero Carbon emission can be achieved even while using fossil fuels by constantly recycling CO2 in the form of regenerated synthetic natural gas. It will not only eliminate CO2 emission but also generate synthetic fuel using renewable Hydrogen without any necessity to exploit fresh fossil fuels. Using renewable Hydrogen as a storage medium or as energy carrier may be expensive due to inherent nature of Hydrogen atom. UN can introduce Carbon Rating as a single tool to measure the Carbon footprint of a specific technology with the lowest or Zero CO2 emission worldwide to start with. They should be more proactive in promoting technologies with highest Carbon rating and encourage countries to adopt such measures.

Friday, April 19, 2019

Why Carbon is inevitable to achieve Zero Carbon emissions?


Generating electricity using fossil fuel is a well-established technology, that has been practiced over several decades all over the world, despite its low efficiency. But this technology inherited certain disadvantages even before it was commercialized such as post combustion emissions, large amount of waste heat, and water intensity. Millions of people died of Carbon pollution over decades. Large scale usage of water both inland and on shore power stations created shortage of drinking water in many parts of the world resulting in desalination technologies creating its own environmental issues. Large scale mining of coal and unsustainable exploitation of oil and gas both on shore and off shore caused enormous environmental pollution. However, such emissions were completely ignored while the world celebrated the discovery of electro-magnetism, steam engine and petrochemicals. Millions of people were employed, and industries grew worldwide. Energy became synonymous with security of a nation. Population grew exponentially. However, we have reached a point in the history of mankind and all great discoveries once acclaimed as human achievements have started a new painful chapter of warming globe and changing climate for new generations to deal with. It is a great challenge of our time, but new generation can take this challenge and convert them into opportunities. The past lessons can show them a new clean and sustainable pathway while dealing with ever increasing population growth. The challenge for the new generation is to curtail and eliminate Carbon pollution completely while meeting the energy demand in a time bound manner because we are running out of time. Currently renewable energy generation is too low to meet these challenges within the time frame to avert disastrous consequences scientists predict. Renewable Hydrogen is a potential substitute for fossil fuel to eliminate Carbon pollution but that will not solve our current problem soon because renewable energy generation is too small and too slow while our energy demand is huge. Battery technology is only a storage technology and without a base load power generation all other forms of technologies will not meet our current challenges. I am not discounting the potential of renewable energy and its critical role in the future energy mix but that alone will not solve the current crisis. Hydrogen is a weak and unstable atom and it requires a backbone such as Carbon. That is why Hydrogen do not exist in a free state in Nature, but it exists in the form of water or natural gas. Therefore, it is only logical to convert renewable hydrogen into renewable natural gas so that it can be used as a fuel as we have been using for decades. It does not require to create a special type of infrastructure such as required for Hydrogen or any storage technologies. Our focus should be to achieve Zero Carbon emission in the shortest time scale possible while generating a base load power of 24 x7 using a renewable energy source. It looks like a daunting task but, it is not too big a challenge to overcome. In fact, the technologies are already available, and we are almost there to achieve the above, but governments should understand the challenge and its gravity and extend all the support it requires. Government around the world should implement the following with great urgency to achieve the above objectives. 1.Tax Carbon with immediate effect and minimum tax should be $500/ Mt of CO2 emitted. It should be centrally monitored by government agencies with appropriate technology implementations. 2. Encourage Oxy combustion technologies for coal, oil and gas-based power plants with incentives to eliminate emissions pollution and reduce the cost of Carbon capture. 3. Encourage large scale deployment of super critical Carbon dioxide power generation technologies with liberal grants and low interest loans for research and development of super critical CO2 technologies using Brayton cycle using fossil fuels with Zero Carbon emission. 4.Encourage large scale deployment of SNG plants using CO2 and renewable Hydrogen. By using the above steps all fossil fuel-based power plants existing and operating can be converted and continue to generate base load power 24 x7 with Zero Carbon Emission within a time frame. Simultaneously it will generate large scale renewable hydrogen and renewable synthetic natural gas which can generate base load power with Zero Carbon emission. Such Zero emission power plants can then power all electric and fuel cell cars and eliminate Carbon pollution completely from our roads. The above implementation will create millions of jobs worldwide! The greatest advantage of these technologies is to recycle Carbon indefinitely while generating power using renewable natural gas with Zero Carbon emission and fresh fossil fuel usage will be gradually eliminated from our planet earth.

Friday, December 18, 2015

Decarbonizing Planet Earth with Carbon


“The method adopted in Vedanta to impart the knowledge of Brahman is known as the method of superimposition (adhyaaropa) and subsequent negation (apavaada). In the Bhashya, Bhagavatpada says, “The transmigrating self is indeed Brahman. He who knows the self as Brahman which is beyond fear becomes Brahman. This is the purport of the whole Upanishad put in a nutshell. It is to bring out this purport that the ideas of creation, maintenance and dissolution of the universe, as well as the ideas of action, its factors and results were superimposed on the Self. Then, by the negation of the superimposed attributes the true nature of Brahman as free from all attributes has been brought out. This is the method of adhyaaropa and apavaada, superimposition and negation, which is adopted by Vedanta.” (Ref: What are Upanishads? : An over view by S.N. Sastri on Luthur.com) The analogy that is often used to describe the process of superimposition and negation is that of ‘using a thorn to remove a thorn’. Finally, when the last thorn is removed, the thorn used to remove it is thrown away as well. Similarly, Carbon can be used to reduce carbon emission while power is generated! Let us consider the issues of Carbon emission and global warming resulting in climate change in the above context. Recent conference in Climate change held in Paris is acclaimed to be a success to the planet earth collectively adopted by 195 countries both developed and developing. In a nutshell they all have agreed to reduce their carbon emissions to limit the global warming to less than 2C or even 1.5 between 2030 and 2050. Is it really practical to achieve the above target given the nature of reduction and the complexity of imposing such a reduction within the time frame? It is a big question mark. The only practical method to reduce CO2 is by using Hydrogen CO2 + H2----> CO + H2O and then convert CO into a useful product such as Urea NH2CONH2 a fertilizer. Production of Urea requires additional Hydrogen which is again obtained by combustion of fossil fuel resulting in CO2 emission. Moreover, CO2 will eventually be released at the point of usage of urea later. While trying to reduce Carbon emission one will end up with more Carbon emission in the atmosphere.
The carbon emission from power plants can be substituted with renewable energy sources such as wind and solar at a very high cost but how the emissions from chemical plants such as urea or from automobile emissions, steel plants and cement plants be contained? We should also remember that silicon wafer to produce solar panels consume large amount of power which now comes invariably from fossil fuels. There is a long list of such plants emitting Carbon every day from all over the world. But there is a possibility to reduce emissions substantially by converting CO2 emissions from power plants into a synthetic fuel which can then substitute fossil fuel to continue power generation. The CO2 resulting from combustion of synthetic fuel will be recycled in the same manner mentioned above thus completing a cycle. To convert CO2 into a synthetic fuel we will require Hydrogen either by renewable sources or non-renewable sources. The non-renewable sources for Hydrogen cannot be a long term solution but renewable Hydrogen is very expensive at this stage. Therefore, Hydrogen is the only source which will not only help reduce Carbon emissions but also help eliminate Carbon completely from planet earth. Renewable Hydrogen is the key to decarbonize the planet earth. However, it may be possible to decarbonize the planet temporarily by using Hydrogen derived from fossil fuel without emitting CO2! It is not just a theory but practical because the technology has already been tested! In this process the Carbon will remain in the loop where it will neither be buried nor emitted into the atmosphere but constantly recycled.

Tuesday, April 29, 2014

“Petrol from seawater “, a Carbon neutral fuel to mitigate climate change !


Recent news from USA has got the attention of many people around the world. “Scientists with the United States Navy say they have successfully developed a way to convert seawater into jet fuel, calling it a potentially revolutionary advancement. Researchers at the Naval Research Laboratory (NRL) developed technology to extract carbon dioxide from seawater while simultaneously producing hydrogen, and then converted the gasses into hydrocarbon liquid fuel. The system could potentially shave hours off the at-sea refueling process and eliminate time spent away from missions.” They estimate the cost of the jet fuel will be anywhere between $3 and $6 per gallon. It may not be able to compete with traditional petroleum sources due to high energy requirement. However, the main attraction of this process is to extract Carbon dioxide absorbed by the ocean to avoid acidification and to mitigate climate change while making petrol as a Carbon neutral fuel. Ocean has become a rich source of Carbon (Carbon sink) absorbing excess atmospheric Carbon dioxide caused by human beings. Generating Carbon neutral fuel such as SNG (synthetic natural gas), diesel and petrol from air and sea water will be the fastest way to reduce Carbon from the atmosphere. Probably Governments, business and industries will embarrass this concept much quicker than any other mitigating methods simply because it is a revenue generating proposition with a potential to earn carbon credit. Carbon-neutral fuel is a synthetic fuel (including methane, gasoline, diesel fuel, jet fuel or ammonia) that is produced using carbon dioxide recycled from power plant flue exhaust gas or derived from carbonic acid in seawater and renewable Hydrogen. Such fuels are potentially carbon-neutral because they do not result in a net increase in atmospheric greenhouse gases. It is a Carbon capture and recycling (CCR) process. “To the extent that carbon-neutral fuels displace fossil fuels, or if they are produced from waste carbon or seawater carbonic acid, and their combustion is subject to carbon capture at the flue or exhaust pipe, they result in negative carbon dioxide emission and net carbon dioxide removal from the atmosphere, and thus constitute a form of greenhouse gas remediation. Such power to gas carbon-neutral and carbon-negative fuels can be produced by the electrolysis of water to make hydrogen used in the Sabatier reaction to produce methane which may then be stored to be burned later in power plants as synthetic natural gas, transported by pipeline, truck, or tanker ship, or be used in gas to liquids processes such as the Fischer–Tropsch (FT) process to make traditional fuels for transportation or heating. Carbon-neutral fuels are used in Germany and Iceland for distributed storage of renewable energy, minimizing problems of wind and solar intermittency, and enabling transmission of wind, water, and solar power through existing natural gas pipelines. Such renewable fuels could alleviate the costs and dependency issues of imported fossil fuels without requiring either electrification of the vehicle fleet or conversion to hydrogen or other fuels, enabling continued compatible and affordable vehicles. A 250 kilowatt synthetic methane plant has been built in Germany and it is being scaled up to 10 megawatts.” (Wikipedia). We have been writing about renewable hydrogen (RH) for the past couple of years and often use the phrase, “Water and energy are two sides of the same coin” because we can mitigate climate change using renewable hydrogen (RH) even while the fossil fuel economy can carry on as usual. By generating Carbon neutral fuels using excess Carbon from air and sea and hydrogen from water (even seawater) using renewable energy sources, the problem of global warming and climate change can be solved because we will not be adding any further Carbon into the atmosphere than what it is today! Instead of generating solar and wind power and storing them in batteries it will be prudent to generate Carbon neutral fuel from CO2 already available in the system and use them as usual. Meanwhile Hydrogen based power generation and transportation can be developed as a long term solution. Fossil- fuel fired power plants produce CO2 (Carbon dioxide) which could be captured and converted to CO (Carbon monoxide) for production of synthetic fuels. CO2 can be converted to CO by the Reverse Water Gas Shift Reaction, CO2 + H2--> CO + H2O. CO could then be used in the F-T reaction with additional hydrogen from water-splitting to produce synthetic fuel such as diesel and petrol as carbon neutral fuels. Synthetic fuel by CO2 Capture + H2 from Water-splitting: Reverse Water Gas Shift CO2 + H2 ----> CO + H2O F-T reaction CO + 2H2 ----> CH2 + H2O Water-splitting 3H2O + Energy --> 3H2 + 3/2O2 Net reaction CO2 + H2O + Energy ---> CH2 + 3/2O2 In this case, no coal is needed at all, and CO2 is consumed rather than produced. The excess O2 (oxygen) would be used in the fossil power plant that provides the CO2, simplifying CO2 capture. There is currently considerable effort underway on developing CO2 capture systems for new and extant power plants. The increasing concern with Global Climate Change suggests that there is a reasonable likelihood of such plants operating in the timeframe associated with synthetic fuel from carbon dioxide. Such a synergistic system has the potential to significantly reduce our current emissions of CO2 since the carbon in the coal is used once for power production and then again for liquid hydrocarbon fuel synthesis. Synthetic fuel plant with capacities as low as 1000 barrels/day are commercially feasible using specially designed micro-reactors as shown in the attached photograph.(Ref:velocys system). Utilizing carbon dioxide from sea and air is the smartest way to mitigate climate change while maintaining fossil fuel based power plants and automobiles without any change or modifications. The same technique can also be applied for biomass gasification plants.

Sunday, June 24, 2012

Renewable Hydrogen for remote power supply


PV solar is expanding as a potential renewable energy source for individual houses, and the cost of solar panels are slowly coming down as the volume of production increases. However, the intermittent nature of solar energy is still an issue, especially for off grid and remote locations. Now solar energy is stored using lead acid batteries for such applications and inverters become part of the system. The capacity of the battery bank is designed to meet the electrical demand and to absorb the fluctuation of the energy generated by solar panels and it varies from location to location. This method stores the electrical energy generated by PV solar in the form of DC current and delivers it in the form of AC current. Though this method is the simplest one for remote locations, storing solar power in the form of Hydrogen is more economical and environmentally friendly in the long run. Solar energy can directly be used to generate Hydrogen using solid polymer electrolyzers and stored in cyclinders.The stored Hydrogen can then be used to fuel a stationary Fuel cell to generate power onsite. One can design a system by integrating various components in such a way; the Hydrogen generated by solar energy is used to generate power on site as and when required. By this method one can generate required power throughout the day 24x7 irrespective of the availability of sun. The system integration involves various components supplied by various manufacturers with various specifications and the success of a system depends on the careful design using data acquired over a period of time on a specific location. Many winds to Hydrogen projects also have been tested in locations around the world.NREL (National renewable energy laboratory, USA) has conducted number of tests by integrating various components such as PV solar and wind turbines with Electrolyzers (both PEM electroylzers and alkaline electrolyzers) and Hydrogen IC engines for remote power generation as well as for fuelling vehicles with Hydrogen. Though the cost of this system is still expensive, such integration offers enormous potential as a clean energy source for remote locations without any grid power. When one takes into account the fluctuating oil prices, cost of global warming, cost of power transmissions and losses during long distance power transmission from fossil fuel power plants, Renewable Hydrogen offers the best and sustainable alternative to fossil fuels. Such a system offers complete independence, energy security, reliability and fixed power tariff. System integration of renewable energy sources for Hydrogen production and onsite power generation using Fuel cell or Hydrogen engine is the key to a successful deployment of solar and wind energy for rural electrification and to remote islands. Such system will offer greater return on investment even to supply power to the grid based on power purchase agreements with Government and private companies. Renewable Hydrogen is the only viable solution for clean power of the future and sooner we embrace this integrated solution better for a cleaner future. Government and private companies investing on oil and gas explorations can focus their attention in developing renewable Hydrogen based solutions so that the cost of Hydrogen can become competitive to fossil fuel. Once the cost of Hydrogen reaches parity with cost of fossil fuel then, it will set the beginning of a green revolution in clean energy.

Thursday, April 26, 2012

Recycling Carbon emissions to Gasoline production


Nature has a wonderful way of capturing Carbon and recycling it through a process called ‘carbon cycle’ for millions of years. The greenhouse gases in the atmosphere were restricted within certain limits when it was left to Nature. But when human being started burning fossil fuels to generate power or to run cars, the GHG emission surpassed the limit beyond a point where global warming became an issue. The GHG level has increased to 392 ppm level for the first in our long history. Many Governments and companies are exploring various ways and means to reduce greenhouse emissions to avoid global warming. Some Governments are imposing taxes on carbon emission in order to reduce or discourage such emissions. Others are offering incentives to promote alternative energy sources such as wind and solar. Some companies are trying to capture Carbon emission for sequestration. While we try to capture Carbon and store them underground, there are many potential commercial opportunities to recycle them. This means the Carbon emission is captured and converted into a commercial fuel such as Gasoline or Diesel or Methane so that future sources of fossil fuels are not burnt anymore. But this is possible only by using ‘Renewable Hydrogen’. Hydrogen is the key to reduce carbon emission by binding carbon molecules with Hydrogen molecule, similar to what Nature does. When NASA plans to send a man to Mars they have to overcome certain basic issues. Mars has an atmosphere with 95% Carbon dioxide, 3% Nitrogen, 1.6% Argon and traces of oxygen, water and methane.Nasa is planning to use Carbon dioxide to generate Methane gas to be used as a fuel and also generate water by using the following reaction. CO2 + 4H2-----CH4 + 2 H2O, 2H2O-------2H2 + O2 The water is electrolyzed to split water into Hydrogen and Oxygen using solar power. The resulting Hydrogen is reacted with Carbon dioxide from Mars to generate Methane gas and water using a solid catalyst. This methanation reaction is exothermic and self sustaining. How this can be achieved practically in Mars in those conditions are not discussed here. But this is a classical example on how the Carbon emission can be tackled to our advantages, without increasing the emissions into the atmosphere. There are several methods available to convert Carbon emission in to valuable products including gasoline. The reaction of the methane with water vapor will result in Methanol. 2H2 + CO-------- CH3OH On Dehydration, 2CH3OH ----- CH3COCH3 + H2O.Further dehydration with ZSM-5 Catalyst gives Gasoline 80% C5+ Hydrocarbon. Gas to liquid by Fischer-tropic reaction is a known process. Carbon dioxide is also a potential refrigerant to substitute CFC refrigerants that causes Ozone depletion. Carbon recycling is a temporary solution to mitigate Greenhouse gas emission till Hydrogen becomes an affordable fuel of the future. It depends upon individual Governments and their policies to make Hydrogen affordable. Technologies are available and only a political will and leadership can make Hydrogen a reality.

Saturday, April 21, 2012

Carbon capture or Carbon recycle?


We live in a carbon constrained world where carbon emission is considered as the biggest challenge of the twenty first century. We unearthed fossil fuel which Nature buried for millions of years and burnt them for our advantage to generate power and to run our cars. Scientists pointed out that the unabated emission of greenhouse will cause the globe to warm with dire consequences.This came as an ‘inconvenient truth’ to industries and Governments around the world. However, economic consequences of stopping fossil fuels outweiged the impact of global warming. Governments were in a precarious situation and were unable to take a concrete policy decision. Popular Governments were not willing to risk their power by taking ethical decisions and opted for popular decision to maintain their growth. Then the financial crisis became an issue, which has nothing to do with greenhouse emission or global warming. Yet, the economic and industrial growth stumbled in many developed countries and unemployment skyrocketed. Governments are caught in a situation where they need to take a balanced view between an ethical decision and economic decisison.The overwhelming evidence of global warming and their consequences are slowly felt by countries around the world by natural disasters of various sizes and intensities. Some scientists suggested that there was nothing wrong using fossil fuels; we could continue with greenhouse emission without risking the economic growth by capturing the carbon and burying them underground. Carbon sequestration and clean coal technologies became popular and more funds were allocated to them than renewable energy development.Countires like India and China were not in a hurry to discontinue fossil fuels but continued to make massive investments on coal fired power plants. They neither try to capture carbon nor bury them, but continue to emit carbon claiming that it is their turn of economic growth and right to emit carbon emission. The chief of UN panel on climate change headed by an Indian has no say in the matter.Politicians push scientists into the background whenever the truth is inconvenient to them. How feasible in the carbon sequestration technology and what is the cost? Even if we can come up with a successful technology of capturing carbon and burying them underground, there will be a cost involved. This cost will invariably be passed on to the consumer which will eventually increase the cost of energy. Constraining carbon emission without incurring a cost can only be a dream. Capturing carbon emission is nothing new; Carbon dioxide is absorbed by solvents like MEA (Monoethanolamine) in many chemical industries. The absorbed carbon dioxide can be stripped free of solvent and the solvent can be recycled. This carbon dioxide can be treated with Ammonia to get Urea, a Fertilizer. But the source of Hydrogen can come only from renewable energy sources. That is why ‘Renewable Hydrogen ‘is the key to solve global warming problem. We can produce Urea from “captured Carbon” and ‘Renewable Hydrogen’ so that we can reduce a substantial quantity of greenhouse emission. Carbon recycling is a sustainable solution than Carbon capturing and burying. Countries like India who depend upon import of Urea for their agriculture production should immediately make Carbon recycling into Urea production mandatory. It is a win situation for everybody in the world.

Sunday, April 15, 2012

New Hydrogen atom- a source of cheap energy?

Hydrogen has been accepted as a source of clean energy for many reasons. Hydrogen can completely eliminate anthropic greenhouse gas emission into the atmosphere and stop global warming. It has high energy content than any other fossil fuels we are currently using, making it an efficient fuel. The combustion product of Hydrogen is only water which is recyclable. Many individuals, Governments and institutions around the world are trying develop cheaper methods of generating Hydrogen from various sources both renewable as well as non-renewable. The non-renewable sources are supposed to facilitate a smooth transition from fossil fuel economy to Hydrogen economy. However, all attempts to generate Hydrogen at a cost lower than the projected cost of $ 2.50 per kg by DOE has not been successful, even though many recent technologies are promising. Meanwhile massive investments are made on renewable energy sources including wind, solar and biological all over the world. Generating Hydrogen from water using Solid Polymer Membrane Electrolyzer is a known technology using renewable energy sources. One can easily deploy such systems for commercial applications even though it is currently expensive. Many individuals and institutions are also claiming ‘free energy’ sources with or without generating Hydrogen. In some cases researches are claiming an abnormal production of Hydrogen using ‘Cold Fusion’ or ‘Plasma electrolysis’ of water, as much as 800% more than the theoretical values. Some companies claim low energy consumption using photo- catalyst to generate Hydrogen using direct sunlight and water. Hydrogen generation using renewable sources is a distinct possibility to reduce the cost of Hydrogen in the long run. However, the world is in hurry to develop a cheap and sustainable method of Hydrogen generation without any greenhouse gas emissions. One US based company is claiming to have invented a new Hydrogen atom which has not been reported previously in the literature. According to the inventor, this new atom of Hydrogen is called ‘Hydrino’.He has presented a detailed theory called ‘Grand Unified Theory’ that predicts catalysts that allow energy to be extracted from lower energy state of Hydrogen atom. They have demonstrated the process using a proto type in the laboratory and their claims have been validated by an independent Laboratory after conducting trial runs and analyzing the results using spectrum analysis and other techniques. The process involves generation of Hydrogen by using electrolysis of water. The resulting Hydrogen is then reacted with a proprietary solid catalyst developed by the company. According to the company, “Since certain proprietary catalysts cause the hydrogen atoms to transition to lower-energy states by allowing their electrons to fall to smaller radii around the nucleus with a release of energy that is intermediate between chemical and nuclear energies, the primary application is as a new primary energy source. Specifically, energy is released as the electrons of hydrogen atoms are induced by a catalyst to transition to lower-energy levels (i.e. drop to lower base orbits around each atom's nucleus). The lower-energy atomic hydrogen product called "hydrino" reacts with another reactant supplied to the reaction cell to form a hydride ion bound to the other reactant to constitute a novel proprietary compound. Alternatively, two hydrinos react to form a very stable hydrogen-type molecule called molecular hydrino. Thus, rather than pollutants, the byproducts may have significant advanced technology applications based on their stability characteristics. For example, hydrino hydride ions having extraordinary binding energies may stabilize a cation (positively charged ion of a battery) in an extraordinarily high-oxidation state as the basis of a high-voltage battery. Further, significant applications exist for the corresponding molecular hydrino wherein the excited vibration-rotational levels could be the basis of a UV laser that could significantly advance photolithography and line-of-sight telecommunications. A plasma-producing cell based on the extraordinarily energetic Process has also been developed that may have commercial applications in chemical plasma processing and as a light source.” The company claims that an average generating capacity of a system will be 1000kw, with installed cost at $1000/kw with fuel cost at less than $0.001/kw with zero greenhouse emission.The solid catalyst is regenerated and recycled. The cost of Hydrogen from electrolysis becomes insignificant due to generation of large excess thermal energy, to generate power. The above claims are too attractive to ignore and it could be a game changer in the energy industry. The output energy is more than the theoretical values calculated, thus violating the Law of Thermodynamics. This excess energy is attributed to the presence of ‘Hydrino’. However, one has to be open to new ideas because science is ever-changing and even well-established theories and concepts are challenged as Science evolves with new discoveries and inventions.

Sunday, April 1, 2012

Why should you choose Photovoltaic Hydrogen over Photovoltaic battery?

Photovoltaic (PV) power is becoming popular worldwide as an alternative to grid power for various reasons. It gives an energy independence and freedom, it helps reduce greenhouse gas emission and combat global warming, it helps people taking advantage of various Government subsidies and incentives, and it also generates some revenue by selling surplus power back to the grid. At the end of the period you own the system and claim depreciation and some tax benefits. All these compelling factors may motivate people to opt for PV solar power. But you should also do some maths and make a cost benefit analysis to choose a right system for you. When there is a good sunshine day after day and throughout the year, PV solar is a good proposition and can be really rewarding. Unfortunately, that is not the reality. There may be many cloudy, rainy and fogging days in a year and your PV solar capacity may be overestimated or underestimated. You know the actual data only after one or two years of life experience. It is a long term financial and ethical decision one has to make and the decision should be absolutely right. You can make such a decision by carefully examining all the factors, not just by looking at the initial cost but looking at operating and maintenance costs during the life cycle and all the costs and benefits associated with them. Storage batteries are inevitable in PV solar systems, especially for grid independent systems. Even with grid connected PV solar system the design and installation of a correct battery bank, controllers and rectifiers are important issues. In this article we will discuss about grid independent system because many developing countries in Africa and Asia do not have 24x7 uninterrupted grid power supplies. Many people living in islands have to manage their own power by using diesel generators. This is the stark reality. Let us assume that you design a system assuming a daily average power consumption of 25,000 kwhrs/day, which is suitable even for a medium size family in US. We made an optimum design study between two systems; first containing PV solar,battery,controlle for grid independent power supply; and second system with PV solar, battery, water Electrolyzer,Hydrogen storage and PEMFuel cell and a rectifier for grid independent system, based on the same power consumption of 25,000kwhrs/day. You can clearly see the difference between the two systems by the following data. This financial analysis was made assuming there is no Government subsidies and incentives. Grid independent system with battery storage for 25,000kwhrs/day power: Total NPV (net present value):$ 342,926 Levelized cost of energy: $2.94/kwhrs Operating cost/yr: $22,764 Grid independent system with Hydrogen storage for 25,000kwhrs/day power: Total NPV (net present value): $ 169,325 Levelized energy cost: $ 1.452/kwhrs Operating cost/yr: 8,330 The number of batteries required in the first case is 17 numbers. In the second case, number of batteries required is only 2. Obviously, the levelized cost of power using PV Hydrogen (storage) is less than 50% of the power generated using PV battery (storage) for the same energy consumption of 25,000kwhrs/day. The operating cost is only one third for PV Hydrogen system compared to battery system. Batteries are indispensable in any renewable energy system but reducing their numbers to the lowest level is important, when the life of the system varies from 25 years to 40 years. The numbers and the cost of battery will make all the difference.

Monday, March 19, 2012

How to power your home and fuel your car with Hydrogen?

There is a general opinion that Hydrogen is dangerous or explosive; people are often reminded of Hindenburg accident or Hydrogen bombs. Hydrogen is as safe as Gasoline or Butane gas. It should be handled with care like any combustible material. We have used Hydrogen in industries for so many decades and transported by pipelines across thousands of kilometers; the methods and procedures of handling Hydrogen is well established. It is a very light, colorless and odorless gas and it can easily escape into the atmosphere. Hydrogenation of vegetable oils for production of certain Margarines is one of the classical industrial examples of Hydrogen usage. When 100m3 Hydrogen is compressed to 10,000psi pressure, it is reduced to just 0.163 m3 by vlume.That is how the Hydrogen storage space is reduced in passenger cars. This volume of gas can give a mileage of 652 miles using Fuel cell power. The only emission is just pure water vapor! No noise, no smoke and it is entirely a new experience driving a Hydrogen Fuel cell car. Powering your home with Hydrogen or fuelling your Fuel cell car is not very difficult. It is expensive compared to grid power for two simple reasons. Grid power is generated by power generation companies somewhere else using coal, oil or gas and transmitted across to millions of people.Therefore investment on power generation is shared by millions of people through their monthly energy bills. When you use the grid power, you do not pay any large sum except, a small deposit of few hundred dollars towards connection fee, and you pay your bills based on your monthly electricity usage. But when you try to generate your own power using a solar panel or Fuel cell then you have to make an investment fully upfront. Of course your bank can help financing the system. However, when you calculate the energy cost over the life period of 25 years, you can clearly see the value of such investment. The grid power cost will only increase and never decrease while your generation cost will decrease as the time passes. The future energy cost is likely to increase substantially due to various factors. You can export surplus power to the grid and your payback time will be reduced as the energy cost increases. The first step in powering your home is to calculate your power requirements accurately in terms of watt.hrs.How many appliances you will be using and how many hours you will using each of these appliances per day. Suppose you estimate 15,000 watt.hrs/day or 15kwhrs/day of power, and then a small Fuel cell consuming 1 Kg/day of Hydrogen or 30 kgs/month of Hydrogen will be sufficient to meet your power demands. Similarly you can calculate the amount of Hydrogen you will be using as a fuel for your Fuel cell car. For example if you will be driving your Fuel cell car for 1000 miles per month, then your Hydrogen requirement will be about 14 kgs/month. Your Hydrogen requirement per month for both power and car together will be 44 kgs only. Your total power requirement to generate the above Hydrogen will be 2464 kwhrs/month costing less than $250 per month for both power and fuel. Of course, you need to calculate other fixed costs on the investment. You can export your solar power at a higher tariff to the Government and import your power requirement from the grid during off-peak season at a lower tariff and generate Hydrogen and store it. You can generate your power as and when you need, and you are in complete control of your situation, even if there is a blackout due to grid failure!

Thursday, March 15, 2012

Hydrogen is cheaper than Gasoline and Diesel

There is a general opinion that Hydrogen is currently very expensive compared to Gasoline and Diesel. It depends on how you generate Hydrogen. We have been using Gasoline and Diesel for several decades and actual cost of crude oil is much lower than what we are paying for Gasoline and Diesel at the service stations. Crude oil is formed naturally and all the costs involved are for pumping, transportation and refining. The cost of energy spent on transportation and refining is also comparatively low. It is the geopolitical situation in the world, supply demand gap, Government taxes and levies, inventory levels, financial market and distributors play a key role in fixing the price of these fuels. Hydrogen can be generated from tap water without involving fossil fuels at all. But Governments are spending on research and development of Hydrogen generation using fossil fuels such as natural gas and coal. It is understandable that these sources are suitable for bulk production of Hydrogen on an industrial scale. We will also be able to use existing fossil fuel infrastructure to the maximum extent. But the flip side of this approach is Hydrogen generated by this route is still not pure enough to meet Fuel cell requirements. This Hydrogen may be suitable for Hydrogen combustion engines. Why they are not suitable? For example, Hydrogen is generated from natural gas by steam reforming,Syngas is generated as an intermediary product which is a mixture of Hydrogen and Carbon monoxide; but also other impurities present in natural gas such Sulfur,Phosphrous and Mercaptans etc.Natural gas has to be purified to remove all these impurities before it can be subject to steam reformation. In spite of an elaborate purification methods adopted, Fuel cell suppliers are reluctant to guarantee the life of their Fuelcell.The Fuel cell uses expensive Platinum as a catalyst which can be readily poisoned by the presence of impurities in Hydrogen, produced from natural gas. This is one of the main reasons why Hydrogen becomes expensive by this route. Industries can pay high cost for this Hydrogen, but ordinary citizens cannot afford to pay. Hydrogen can be generated directly from tap water by simply electrolyzing it using a Direct current such as solar and wind. If we use grid power, it requires about 68kwhrs of electricity, costing about $3.40 per Kg of Hydrogen. Assuming Hydrogen will cost about $5 per kg after compression and storage, it is still worth the cost. This Hydrogen will give a mileage of 73.4 miles/kg using Fuel cell car. This is equivalent to 3.67 Gallons of Gasoline costing approximately $13.76 at the rate of $3.75 per gallon. It is very clear that Hydrogen is cheaper than Gasoline or Diesel. At the current price,Gasoline costs 275% more than Hydrogen gas. By converting existing coal and oil based power plants into IGCC, Integrated Gasification and Combined Cycle plants, Government can reduce the current emission levels of greenhouse gases, and at the same time supply electricity at the prevailing rates. We do not have to import oil or gas. Government should fund conversion of coal and oil fired power plants into IGCC plants and create Hydrogen infrastructure, by producing more Hydrogen Fuel cell cars and Hydrogen service stations. By adopting this policy, US Government can bring down the prices of crude oil in the international market which will help reduce the prices of all other petrochemical products like fertilizers, plastics, drugs and cosmetics. The crux of the issue is to divert petroleum products from fuel use to other uses. At the same time Governments can reduce their greenhouse emissions to the level demanded by scientists. By reducing the cost of solar panels to less than $1.00 per watt, Renewable Hydrogen will become a commercial reality and that will be the end of fossil fuels.